94286-86-9

Upstream product

• 61981-44-0 (2R, 3RS)-(+)-1,2,3-heptantriol-1,2-acetonide-3-benzyl ether 
• 87604-52-2 (R)-4-((R)-1-Benzyloxy-pentyl)-2,2-dimethyl-[1,3]dioxolane 
• 654077-33-5 (R)-2-((R)-1-Benzyloxy-pentyl)-1,4-dioxa-spiro[4.5]decane 
• 100-39-0 benzyl bromide 

Downstream Products

• 61981-46-2 Toluene-4-sulfonic acid (R)-3-benzyloxy-2-hydroxy-heptyl ester 
• 85027-73-2 (S)-2-O-benzyl-2-hydroxyhexanal 
• 94286-88-1 [2R,2(1R)]-2-(1-benzyloxy-pentyl)-oxirane 
• 654077-19-7 (4R)-2-methyl-4-benzyloxyoct-2-ene 

Relevant academic research and scientific papers

Diastereoselective Synthesis of syn-Alkanetriols from a Glyceral Derivative via K-Selectride Reduction: Application to the Synthesis of a Pheromone of the Sugarcane Weevils

K-selectride reduction of commercially available D-mannitol derived ketones 2b-i produced the corresponding alcohols 3b-i in good yields and with absolute syn-selectivity in almost all the cases. It was proposed that the bulky cyclohexylidene moiety of 3

Synthesis of the rarely obtained syn-Adducts in the Reaction of Organocopper Compounds with 2,3-O-Isopropylideneglyceraldehyde. Preparation of Optically Active Epoxy Alcohols

Organocopper compounds, prepared from Grignard reagents and copper(I) iodide in tetrahydrofuran-dimethyl sulphide, react with 2,3-O-isopropylideneglyceraldehyde highly stereoselectively (>10:1) affording the rarely obtained syn-addition products which can be readily converted into optically active epoxy alcohols, useful intermediates in organic synthesis.