94286-86-9Relevant academic research and scientific papers
Diastereoselective Synthesis of syn-Alkanetriols from a Glyceral Derivative via K-Selectride Reduction: Application to the Synthesis of a Pheromone of the Sugarcane Weevils
Dhotare, Bhaskar,Salaskar, Avinash,Chattopadhyay, Angshuman
, p. 2571 - 2575 (2007/10/03)
K-selectride reduction of commercially available D-mannitol derived ketones 2b-i produced the corresponding alcohols 3b-i in good yields and with absolute syn-selectivity in almost all the cases. It was proposed that the bulky cyclohexylidene moiety of 3
Synthesis of the rarely obtained syn-Adducts in the Reaction of Organocopper Compounds with 2,3-O-Isopropylideneglyceraldehyde. Preparation of Optically Active Epoxy Alcohols
Sato, Fumie,Kobayashi, Yuichi,Takahashi, Osamu,Chiba, Tsunehisa,Takeda, Yoshiyuki,Kusakabe, Masato
, p. 1636 - 1638 (2007/10/02)
Organocopper compounds, prepared from Grignard reagents and copper(I) iodide in tetrahydrofuran-dimethyl sulphide, react with 2,3-O-isopropylideneglyceraldehyde highly stereoselectively (>10:1) affording the rarely obtained syn-addition products which can be readily converted into optically active epoxy alcohols, useful intermediates in organic synthesis.
