943-59-9Relevant academic research and scientific papers
Method for generating ester through reaction of acyl chloride and 1,2-dichloroethane
-
Paragraph 0023; 0025; 0059; 0060; 0061, (2017/08/30)
The invention discloses a method for generating ester through reaction of acyl chloride and 1,2-dichloroethane. The method comprises the following steps: taking acyl chloride, 1,2-dichloroethane and carbonate as reaction substrates, and taking 4-dimethyla
An Effective Method for the Construction of Esters Using Cs2CO3 as Oxygen Source
Ren, Lanhui,Wang, Lianyue,Lv, Ying,Li, Guosong,Gao, Shuang
supporting information, p. 5172 - 5175 (2015/11/24)
An effective method for the construction of esters from acyl chloride and halohydrocarbon using Cs2CO3 as an oxygen source was achieved for the first time. The methodology has a wide scope of substrates and can be scaled up. The study of a preliminary reaction mechanism demonstrated that the O in the products comes from Cs2CO3 and this esterification proceeds through a free radical reaction. It was also found that CO2 can also be used in this esterification reaction as an oxygen source.
Reaction of 2-Alkyl-2-phenyl-1,3-dioxolans with Iodine Monochloride: Formation of α-Phenylalkanoate Esters
Goosen, Andre,McCleland, Cedric W.
, p. 1311 - 1312 (2007/10/02)
2-Alkyl-2-phenyl-1,3-dioxolans undergo a high-yield transformation into 2-chloroethyl α-phenylalkanoates upon treatment with iodine monochloride in dichloromethane.
