94397-84-9Relevant academic research and scientific papers
PREPARATION OF 1-SILYL- AND 1,3-DISILYL-ADAMANTANES
Pai, Yi-Ming,Wanek, Erich,Weber, William P.
, p. 271 - 276 (1984)
1-Dimethylsilyl- and 1,3-bis(dimethylsilyl)adamantane have been prepared in low yield by Wurtz reaction of dimethylchlorosilane with 1-chloroadamantane or 1,3-dichloroadamantane, respectively.On the other hand, reaction of phenyldimethylsilyllithium with 1-bromoadamantane or 1,3-dibromoadamantane gives essentailly quantitative yields of 1-phenyldimethylsilyladamantane or 1,3-bis(phenyldimethylsilyl)adamantane, respectively.
