Journal of Organometallic Chemistry p. 271 - 276 (1984)
Update date:2022-07-29
Topics:
Pai, Yi-Ming
Wanek, Erich
Weber, William P.
1-Dimethylsilyl- and 1,3-bis(dimethylsilyl)adamantane have been prepared in low yield by Wurtz reaction of dimethylchlorosilane with 1-chloroadamantane or 1,3-dichloroadamantane, respectively.On the other hand, reaction of phenyldimethylsilyllithium with 1-bromoadamantane or 1,3-dibromoadamantane gives essentailly quantitative yields of 1-phenyldimethylsilyladamantane or 1,3-bis(phenyldimethylsilyl)adamantane, respectively.
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(1984)
