944579-56-0Relevant articles and documents
Studies on taxadiene synthase: interception of the cyclization cascade at the verticillene stage and rearrangement to phomactatriene
Chow, Siew Yin,Williams, Howard J.,Pennington, James D.,Nanda, Samik,Reibenspies, Joseph H.,Scott, A. Ian
, p. 6204 - 6209 (2008/02/05)
The cyclization of geranylgeranyl diphosphate (GGDP) to taxadiene catalyzed by taxadiene synthase has been suggested to proceed in stages, involving a transient bicyclic verticillyl carbocation intermediate, which also has been proposed in the biosyntheti