944732-41-6Relevant academic research and scientific papers
Chiral Imidazolidin-4-one with catalytic amount of Dicationic ionic liquid act as a recoverable and reusable Organocatalyst for asymmetric Diels-Alder reaction
Deepa,Yadav, Geeta Devi,Chaudhary, Pooja,Aalam, Mohd Jubair,Meena, Dhan Raj,Singh, Surendra
, p. 64 - 72 (2019/11/20)
Imidazolidin-4-one is used as a recoverable organocatalyst for the asymmetric Diels-Alder reaction in the presence of catalytic amount of dicationic ionic liquid and trifluoroacetic acid as a co-catalyst. The Diels-Alder reaction between model substrate cyclopentadiene and crotonaldehyde gave the product in 95% conversion and 87% ee of the endo-product. The catalyst was shown better reusability when the 20?mol% of dicationic ionic liquid was used and catalyst was reused upto 5 cycles, conversion remains upto 3 recycles but ee of endo-9 was slightly droped.
Polystyrene-supported organocatalysts for α-selenenylation and Michael reactions: A common post-modification approach for catalytic differentiation
Giacalone, Francesco,Gruttadauria, Michelangelo,Agrigento, Paola,Campisciano, Vincenzo,Noto, Renato
scheme or table, p. 75 - 80 (2012/02/03)
Three different resin-supported catalysts have been prepared by using the well established post-modification approach by means of thiol-ene coupling reaction. Two catalysts were tested for the first time in the asymmetric α-selenenylation of propanal, whi
HETEROGENEOUS CHIRAL CATALYST
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Page/Page column 12, (2009/12/04)
The invention provides a heterogeneous catalyst comprising a catalytic group coupled to a mesocellular siliceous foam support. The catalytic group is capable of catalysing a reaction selected from the group consisting of a Friedel-Craft reaction and a Die
Enantioselective catalysis over chiral imidazolidin-4-one immobilized on siliceous and polymer-coated mesocellular foams
Zhang, Yugen,Zhao, Lan,Lee, Su Seong,Ying, Jackie Y.
, p. 2027 - 2032 (2007/10/03)
A highly efficient and enantioselective organocatalyst, imidazolidin-4-one, has been successfully immobilized on siliceous MCF and polymer-coated MCF. The resulting heterogenized catalyst demonstrated excellent catalytic performance and recyclability for
