94514-35-9Relevant academic research and scientific papers
Reactions of Organic Anions, 163. - Reactions of Nitrobenzophenones with Carbanions Containing Leaving Groups. Vicarious Nucleophilic Substitution of Hydrogen versus Darzens or Wittig-Horner Reactions
Makosza, Mieczyslaw,Baran, Janusz,Dziewonska-Baran, Danuta,Golinski, Jerzy
, p. 825 - 832 (2007/10/02)
Carbanions containing leaving groups at the carbanion center react with nitrobenzophenones by two general pathways: addition to the carbonyl group which results in the Darzens or Wittig-Horner reaction and/or addition to the nitroaromatic ring resulting i
REACTIONS OF CHLOROMETHYL PHENYL SULFONE CARBANION WITH NITROBENZOPHENONES. THE VICARIOUS SUBSTITUTION OF HYDROGEN VERSUS THE DARZENS CONDENSATION
Makosza, Mieczyslaw,Golinski, Jerzy,Baran, Janusz,Dziewonska-Baran, Danuta
, p. 1619 - 1622 (2007/10/02)
Carbanion of chloromethyl phenyl sulfone replaces hydrogen atoms o'- and p'- to the nitro group in o-nitrobenzophenone, whereas with p-nitrobenzophenone it enters the Darzens condensation followed by rearrangement and decarbonylation.Reaction course with
