945656-60-0

Upstream product

• 70-11-1 α-bromoacetophenone 
• 6842-36-0 2-(2-hydroxyphenyl)-1,3-dithiane 
• 90-02-8 salicylaldehyde 
• 1037288-04-2 C₁₇H₁₈O₄ 
• 6052-79-5 2-(2-hydroxyphenyl)-1,3-dioxane 
• 945656-70-2 C₁₄H₁₉NO₅ 

Downstream Products

• 17571-11-8 (3-hydroxy-2,3-dihydro-benzofuran-2-yl)-phenyl-methanone 
• 6272-40-8 2-benzoylbenzofuran 
• 1013938-60-7 C₁₅H₁₂O₃ 
• 721-04-0 2-phenoxy-1-phenylethanone 
• 1574474-96-6 (R)-N-((3R,4S)-3-hydroxy-3-phenyl-3,4-dihydro-2H-chromen-4-yl)tert-butylsulfinamide 
• 1574474-95-5 C₁₉H₂₁NO₃S 
• 857362-91-5 3-hydroxy-3-phenyl-chroman-4-one 
• 1108233-70-0 3-phenyl-2H-benzo[e][1,4]dioxepin-5(3H)-one 

Relevant academic research and scientific papers

Enantioselective Synthesis of Chromanones Bearing Quaternary Substituted Stereocenters Catalyzed by (1R)-Camphor-Derived N-Heterocyclic Carbenes

A catalytic asymmetric intramolecular crossed-benzoin reaction for the synthesis of chromanones by novel camphor-derived N-heterocyclic carbenes is described. The corresponding chromanones bearing quaternary stereogenic centers were isolated in high yield

Asymmetric synthesis of novel vicinal amino alcohols via intramolecular ketone- N -sulfinylimine pinacol-type reductive coupling promoted by SmI 2

A novel intramolecular asymmetric ketone-N-sulfinylimine pinacol-type reductive coupling reaction induced by SmI2 was reported. A series of 1-amino-1,2,3,4-tetrahydronaphthalen-2-carbinols were obtained in moderate to good yields with excellent

Rh-catalyzed carbonyl hydroacylation: an enantioselective approach to lactones

This communication describes the design and execution of a novel approach to forming chiral lactones via C-H bond activation. The strategy features an unprecedented enantioselective Rh-catalyzed hydroacylation of carbon-oxygen double bonds. Representative keto-aldehydes (derived from salicylaldehyde) undergo cyclization with complete regioselectivity to afford seven-membered lactones in great enantiomeric excess (≥99% ee). The basicity of the phosphine ligand is shown to play a critical role in promoting hydroacylation over competitive decarbonylation. Copyright

D-Camphor-derived triazolium salts for catalytic intramolecular crossed aldehyde-ketone benzoin reactions

A series of triazolium salts has been synthesized from d-camphor and found to be efficient catalysts for intramolecular crossed aldehyde-ketone benzoin reactions, affording α-ketols bearing a quaternary carbon center with up to 93% ee. The Royal Society o

Modified chiral triazolium salts for enantioselective benzoin cyclization of enolizable keto-aldehydes: Synthesis of (+)-sappanone B

Equation Presented Asymmetric synthesis of (+)-sappanone B (1), a natural product with a 3-hydroxy chromanone structure, was achieved via enantioselective benzoin cyclization by using a modified Rovis catalyst and triethylamine. This catalyst enabled the