945905-31-7Relevant academic research and scientific papers
Fluoride ion complexation by a cationic borane in aqueous solution
Lee, Min Hyung,Agou, Tomohiro,Kobayashi, Junji,Kawashima, Takayuki,Gabbai, Francois P.
, p. 1133 - 1135 (2007)
The phosphonium borane [p-Mes2B(C6H 4)PMePh2]+ complexes fluoride in water containing 10% methanol with a binding constant of 1.0(±0.1) × 103 M-1 to afford the zwitterion p-Mes
Phase transfer of fluoride ion by phosphonioborins
Agou, Tomohiro,Kobayashi, Junji,Kim, Youngmin,Gabbai, Francois P.,Kawashima, Takayuki
, p. 976 - 977 (2008/02/10)
Two cationic triarylboranes based on phosphonioborin frameworks have been investigated. Electron-withdrawing phosphonio groups enhanced the Lewis acidity of these boranes which capture fluoride ion in aqueous media and transport it into organic phase. Cop
