947527-46-0Relevant academic research and scientific papers
Rhodium-Catalyzed [4+2+1] Cycloaddition of In Situ Generated Ene/Yne-Ene-Allenes and CO
Tian, Zi-You,Cui, Qi,Liu, Cheng-Hang,Yu, Zhi-Xiang
supporting information, p. 15544 - 15548 (2018/10/31)
Reported herein is the first rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and CO to synthesize challenging seven-membered carbocycles fused with five-membered rings. This reaction is designed based on the 1,3-acyloxy mi
Synthesis of functionalized pyrroles via gold(l)-catalyzed aza-Claisen-type rearrangement
Istrate, Florin M.,Gagosz, Fabien
, p. 3181 - 3184 (2008/02/10)
Gold(l)-catalyzed cyclization of pentenynyl allyl tosylamides allows the rapid construction of functionalized pyrroles. The concerted aza-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary cent
