94762-80-8Relevant articles and documents
SYNTHESIS OF dl-SEPTICINE
Iwashita, Takashi,Suzuki, Masahiro,Kusumi, Takenori,Kakisawa, Hiroshi
, p. 383 - 386 (1980)
Cyloaddition reaction of 1-pyrroline 1-oxide with 2,3-bis(3,4-dimethoxyphenyl)butadiene proceeded regioselectively to give two stereoisomeric isoxazolidine derivatives, one of which was converted into septicine by three-step reactions.
Electro-reductive Fragmentation of Oxidized Lignin Models
Yang, Cheng,Magallanes, Gabriel,Maldonado, Stephen,Stephenson, Corey R. J.
, p. 15927 - 15934 (2021/06/30)
Lignin provides a potential sustainable source for production of electron-rich aromatic compounds. Recently, electrochemical lignin degradation via an oxidation/reduction sequence under mild conditions has garnered much attention within the lignin community, as electrochemistry simplifies redox reactions and offers an electron source/sink for synthesis without using stoichiometric oxidants or reductants. This paper describes a fundamental approach for the electrochemical fragmentation of the primary connection in native lignin, β-O-4. Potential-controlled electrolysis enables selective reduction and provides fragmentation products and/or coupling products in isolated yields of 59-92%.