948027-87-0Relevant articles and documents
On the photoreaction of some 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene. Synthesis of N-imidoyl-aziridines
Palumbo Piccionello, Antonio,Pibiri, Ivana,Pace, Andrea,Raccuglia, Rosa Angela,Buscemi, Silvestre,Vivona, Nicolo,Giorgi, Gianluca
, p. 1529 - 1537 (2008/09/17)
The photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process.