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Benzamide, N-acetyl- (6CI,7CI,8CI,9CI) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1575-95-7

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1575-95-7 Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 23, p. 915, 1958 DOI: 10.1021/jo01100a614Tetrahedron, 51, p. 10901, 1995 DOI: 10.1016/0040-4020(95)00666-V

Check Digit Verification of cas no

The CAS Registry Mumber 1575-95-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,7 and 5 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1575-95:
(6*1)+(5*5)+(4*7)+(3*5)+(2*9)+(1*5)=97
97 % 10 = 7
So 1575-95-7 is a valid CAS Registry Number.
InChI:InChI=1/C9H9NO2/c1-7(11)10-9(12)8-5-3-2-4-6-8/h2-6H,1H3,(H,10,11,12)

1575-95-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name N-Acetylbenzamide

1.2 Other means of identification

Product number -
Other names N-Benzoyl-acetamid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1575-95-7 SDS

1575-95-7Relevant academic research and scientific papers

A novel one-pot synthesis of unsymmetrical acyclic imides

Habibi, Zohreh,Salehi, Peyman,Zolfigol, Mohammad Ali,Yousefi, Maryam

, p. 812 - 814 (2007)

A new and convenient method was found for the one-pot synthesis of symmetrical and unsymmetrical linear imides by reaction of aliphatic and aromatic nitriles with acyclic carboxylic anhydrides in the presence of silica sulfuric acid as an active and recyclable reagent. Georg Thieme Verlag Stuttgart.

Conversion of N-Acyl amino acids into imides via oxidative decarboxylation induced by Ag+/Cu2+/S2O8 2- in water

Huang, Wenhua,Wang, Meiling,Yue, Hong

, p. 1342 - 1344 (2008)

N-Acyl amino acids can be converted by oxidative decarboxylation induced by Ag+/Cu2+/S2O82- at room temperature in water into imides in 24-89% yields. Both N-benzoylvaline and N-benzoylleucine gave N-

A solvent effect that influences the preparative utility of N- (silylalkyl)phthalimide and N-(silylalkyl)maleimide photochemistry

Yoon, Ung Chan,Oh, Sun Wha,Lee, Soo Min,Cho, Sung Ju,Gamlin, Janet,Mariano, Patrick S.

, p. 4411 - 4418 (1999)

The photochemistry of selected N-silylalkyl-substituted phthalimides and maleimides has been investigated with the aim of exploring the generality and preparative consequences of an intriguing solvent effect on excited-state reaction chemoselectivities and quantum efficiencies. An example of this effect is found in the photochemistry of N- [(trimethylsilyl)butyl]phthalimide 10, where irradiation in MeCN leads to production of a mixture of four products that arise by excited-state intramolecular hydrogen-atom abstraction. In contrast, the benzoindolizidine 15 is the sole product produced by a single electron transfer (SET)- desilylation pathway upon irradiation of 10 in 35% H2O-MeCN. Another example of this solvent effect is found in the photochemistry of the N-silylpropyl- maleimide 17. Irradiation in MeCN results in the production of the 2+2-dimer 19 whereas the pyrrolizidine 18 is generated exclusively by irradiation of 17 in 35% H2O-MeCN. The results of fluorescence and triplet sensitization experiments suggest that the solvent effect has multiple sources including the control of the nature, reactivity, and intrinsic lifetimes of singlet and triplet excited states of the phthalimide and maleimide systems. The exploratory studies have clearly demonstrated the generality of this solvent effect and how it can be used to enhance the preparative utility of the photochemistry of N-(silylalkyl)phthalimides and N-(silylalkyl)maleimides.

Organophosphine/phosphite-stabilized silver(I) complexes bearing N-acetylbenzamide ligand: Synthesis, characterization and potential application in metal organic chemical vapor deposition

Tao, Xian,Shen, Ke-Cheng,Tang, Qing-Yun,Feng, Meng,Fang, Jiang-Tao,Wang, Yu-Long,Shen, Ying-Zhong

, p. 323 - 329 (2012)

New N-silver(I) acetylbenzamide complexes of type Ln· AgNC9H8O2 (L = PPh3; n = 1, 2a; n = 2, 2b; n = 3, 2c; L = P(OEt)3; n = 1, 2d; n = 2, 2e; n = 3, 2f) were prepared. These complexes were

Method for preparing derivatives of benzamide under microwave condition in aqueous phase

-

Paragraph 0019; 0068, (2019/03/28)

The invention discloses a method for preparing derivatives of benzamide under a microwave condition in an aqueous phase. A coupling reaction is carried out between substituted benzoic acid and amine under the microwave condition in the aqueous phase. The method for preparing the derivatives of benzamide is environmentally friendly, easy and convenient to operate, safe, low in cost and efficient. Compared with the prior art, the method can be applicable to a large number of functional groups, is high in yield, produces fewer by-products, and further is easy to operate, safe, low in cost and environmentally friendly. A formula is shown in the description.

Method for catalytically oxidizing amine to be synthesized into amide through dipyridyl-type manganese catalyst

-

Paragraph 0017-0027; 0055-0057, (2019/06/30)

The invention discloses a methodfor catalytically oxidizing amine to be synthesized into amide througha dipyridyl-type manganese catalyst. According to the method, a dipyridyl manganese complex formedafter coordination of a dipyridyl-type complex and cheap metal manganese serves as the catalyst, clean and environment-friendly hydrogen peroxide serves as an oxidizing agent, oxidation of N ortho-position sp3 C-H bonds catalyzed by the cheap metal manganese is achieved, and the amine is directly oxidized to obtain the amide. Compared with existing methods, the method has the advantages that theadopted catalyst is low in price, the preparing method is simple, raw materials are easy to obtain, the use level of the catalyst is low, the substrate range is wide, the reaction condition is mild, the operation is simple and environmentally friendly, the reaction time is short, the yield is high, the selectivity is high, and the industrialization cost is low.

Palladium-Catalyzed Solvent-Controlled Selective Synthesis of Acyl Isoureas and Imides from Amides, Isocyanides, Alcohols and Carboxylates

Cao, Ming,Liu, Liqiu,Tang, Shi,Peng, Zhiyuan,Wang, Yingchun

supporting information, p. 1887 - 1895 (2019/03/11)

A highly selective synthesis of acyl isoureas and imides from readily accessible amides, isocyanides, alcohols and carboxylates based on reaction solvent selection is described. In the presence of a catalytic amount of [1,1′-bis(diphenylphosphino)ferrocene]dichloropalladium(II) and cupric acetate, treatment of amides and isocyanides in alcohols at 60 °C provided acyl isoureas in high yields. Interestingly, when other solvents such as acetonitrile was used instead of alcohols, imides were exclusively produced in good to excellent yields via direct N-acylation of amides with carboxylates as the acyl sources. This protocol offers an attractive alternative approach toward isoureas and imides. (Figure presented.).

Visible-Light-Driven Oxidation of N -Alkylamides to Imides Using Oxone/H 2 O and Catalytic KBr

Mei, Chong,Hu, Yixin,Lu, Wenjun

, p. 2999 - 3005 (2018/05/25)

Imides are prepared conveniently by visible-light-driven oxidations of various N -alkylamides under mild conditions. The majority of the reactions proceed efficiently by using Oxone as the oxidant in the presence of a catalytic amount of KBr in H 2 O/CH 2 Cl 2 under irradiation by an 8 W white LED at room temperature. Experimental studies suggest that an imine, obtained from the substrate amide via a radical process, is the key intermediate.

A carbonylation reaction of carbon monoxide in the method of preparing amide

-

Paragraph 0024; 0025; 0026; 0027; 0028-0032; 0131-0132; 0147, (2018/07/30)

The invention belongs to the technical field of synthesis of amides, discloses a process for the carbonylation of carbon monoxide in the method of preparing amide, the method is to cheap and easy to obtain the halogenated aromatic hydrocarbon and organic amine compounds as the substrate of reaction, to carbon monoxide as carbonyl source, under light-struck, halogenated aromatic hydrocarbons are cracked to produce free radical, by free-radical addition process to obtain the amide compound. Compared with the traditional carbonylation reaction, the carbon monoxide pressure is extremely low, can react to the atmospheric pressure. This process does not need to rely on any metal catalyst of the booster, mild reaction conditions, environmental protection, with a shorter synthetic route and high utilization efficiency of the atoms, the reaction system with higher substrate tolerance, green sustainable light source as the driving force, the atom economy is high, application prospect.

Transition-Metal- and Halogen-Free Oxidation of Benzylic sp 3 C-H Bonds to Carbonyl Groups Using Potassium Persulfate

Hu, Yixin,Zhou, Lihong,Lu, Wenjun

supporting information, p. 4007 - 4016 (2017/08/29)

Aryl carbonyl compounds including acetophenones, benzophenones, imides, and benzoic acids are prepared from benzyl substrates using potassium persulfate as oxidant with catalytic pyridine in acetonitrile under mild conditions. Neither transition metals nor halogens are involved in the reactions.

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