94816-47-4

Upstream product

• 74-96-4 ethyl bromide 
• 59662-65-6 methylthiomethyl p-tolyl sulfone 

Downstream Products

• 113512-21-3 4-Methylsulfanyl-1-phenyl-4-(toluene-4-sulfonyl)-hexan-3-ol 
• 99946-90-4 1-Methyl-4-(2-methylsulfanyl-1-phenyl-but-3-ene-2-sulfonyl)-benzene 
• 99946-89-1 2-(methylthio)-3-buten-2-yl p-tolyl sulfate 
• 99946-97-1 (E)-3-(methylthio)-2-buten-1-yl p-tolyl sulfate 
• 99946-98-2 (Z)-3-(methylthio)-2-buten-1-yl p-tolyl sulfate 
• 99946-84-6 1-Methyl-4-((E)-1-methylsulfanyl-prop-1-ene-1-sulfonyl)-benzene 
• 99947-00-9 (Z)-3-(methylthio)-4-phenyl-2-buten-1-yl p-tolyl sulfone 
• 99946-99-3 (E)-3-(methylthio)-4-phenyl-2-buten-1-yl p-tolyl sulfone 
• 99946-81-3 1-chloro-1-(methylthio)-1-propyl p-tolyl sulfone 

Relevant academic research and scientific papers

A VERSATILE REAGENT FOR SYNTHESIS OF α-HYDROXY ALDEHYDES AND KETONES --- METHYLTHIOMETHYL p-TOLYL SULFONE

Methylthiomethyl p-tolyl sulfone (1) can be utilized for synthesizing α-hydroxy ketones as well as α-hydroxy aldehydes, the hydroxyl group of which is protected with acetyl, tetrahydropyranyl, or methoxymethyl group.

A Facile Allylic 1,3-Rearrangement of a Sulfonyl Group and Its Application to a Synthesis of α,β-Unsaturated Ketones

A p-tolylsulfonyl group undergoes a SiO2-catalyzed 1,3-rearrangement in a sulfenylated allylic system and this rearrangement can be utylized in novel and convenient syntheses of α,β-unsaturated ketones 6 using 3-(methylthio)-2-propenyl p-tolyl sulfone (1)