99946-99-3

Upstream product

• 99946-90-4 1-Methyl-4-(2-methylsulfanyl-1-phenyl-but-3-ene-2-sulfonyl)-benzene 
• 59662-65-6 methylthiomethyl p-tolyl sulfone 
• 94816-47-4 1-(methylthio)-1-propyl p-tolyl sulfone 
• 99946-84-6 1-Methyl-4-((E)-1-methylsulfanyl-prop-1-ene-1-sulfonyl)-benzene 
• 99946-81-3 1-chloro-1-(methylthio)-1-propyl p-tolyl sulfone 

Relevant academic research and scientific papers

A Facile Allylic 1,3-Rearrangement of a Sulfonyl Group and Its Application to a Synthesis of α,β-Unsaturated Ketones

A p-tolylsulfonyl group undergoes a SiO2-catalyzed 1,3-rearrangement in a sulfenylated allylic system and this rearrangement can be utylized in novel and convenient syntheses of α,β-unsaturated ketones 6 using 3-(methylthio)-2-propenyl p-tolyl sulfone (1)