94902-60-0Relevant academic research and scientific papers
Synthesis of L-α-phosphatidyl-D-myo-inositoi 5-phosphate and L-α- phosphatidyl-D-myo-inositol 3,5-bisphosphate
Peng, Jirong,Prestwich, Glenn D.
, p. 3965 - 3968 (2007/10/03)
Two new 5-phosphorylated phosphatidylinositols have been synthesized from methyl α-D-glucopyranoside as the chiral precursor. These new PtdInsP(n)s have been recently detected in mammalian cells.
Regioselective Reductive Ring-opening of 4-Methoxybenzylidene Acetals of Hexopyranosides. Access to a Novel Protecting-group Strategy. Part 1
Johansson, Rolf,Samuelsson, Bertil
, p. 2371 - 2374 (2007/10/02)
Reduction of fully protected 4,6-O-(4-methoxybenzylidene) hexopyranosides with sodium cyanoborohydride-trifluoroacetic acid in NN-dimethylformamide, or trimethylsilyl chloride in acetonitrile, gives the 6- and 4-O-(4-methoxybenzyl) ethers, respectively, in good yield and good regioselectivity.The 4-methoxybenzyl ether linkage in products containing benzyl ethers or other protective groups is selectively cleaved upon treatment with cerium(IV) ammonium nitrate in aqueous acetonitrile.
