949463-72-3

Upstream product

• 1127645-28-6 C₇₃H₁₂₄N₂O₇Si₃ 
• 1147745-89-8 (E,14S)-N-((3S,11bR)-9,11-bis(benzyloxy)-2,3,4,6,7,11b-hexahydro-4-oxo-1H-pyrido[2,1-a]isoquinolin-3-yl)-14-hydroxyoctacos-17-enamide 
• 949463-54-1 (3S,11bR)-3-amino-9,11-bis(benzyloxy)-2,3,6,7-tetrahydro-1H-pyrido[2,1-a]isoquinolin-4(11bH)-one 
• 1337879-11-4 C₄₆H₉₈O₅Si₃ 
• 1337879-18-1 (4S,5S)-1-(benzyloxy)pentadecane-4,5-diol 
• 1337879-19-2 (4S,5S)-1-benzyloxy-4,5-bis-(tert-butyldimethylsilanyloxy)pentadecane 
• 1337879-20-5 (4S,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)pentadecan-1-ol 
• 1337879-13-6 (4S,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)pentadecanal 
• 1337879-21-6 (4R,7S,8S)-7,8-bis-(tert-butyldimethylsilanyloxy)octadec-1-en-4-ol 
• 1337879-12-5 (4R,7S,8S)-4,7,8-tris(tert-butyldimethylsilanyloxy)octadec-1-ene 
• 1337879-22-7 C₅₃H₁₀₂O₅Si₃ 
• 1337879-24-9 C₇₃H₁₂₄N₂O₇Si₃ 
• 100-39-0 benzyl bromide 
• 261178-56-7 benzyl 11-dodecenoate 

Relevant academic research and scientific papers

Formal synthesis of schulzeines B and C

A formal synthesis of schulzeines B and C, marine natural products with inhibitory effect against α-glucosidase, has been achieved. The key reactions of the synthesis are N-acyliminium ion cyclization, Sharpless asymmetric dihydroxylation, olefin cross me

Enantioselective synthesis of schulzeines B and C via a β-lactone-derived surrogate for bishomoserine aldehyde

Enantioselective syntheses of the glucosidase inhibitors schulzeines B and C were achieved by employing a Pictet-Spengler reaction of a β-lactone-derived, masked bishomoserine aldehyde. Subsequent Corey-Link reaction unveiled an α-azido acid enabling cycl

Total syntheses of schulzeines B and C

(Chemical Equation Presented) Schulzeines B (2) and C (3) were synthesized by a convergent strategy using epimeric tricyclic lactam building blocks, 4 and 5, and the C28 fatty acid side chain 6. Syntheses of tricyclic lactams (4/5) were achieved by Bischl