950193-44-9

Basic information

• Product Name: FeC₅H₅C₅H₄C₂C₆H₄C₆H₄NO₂
• CAS NO: 950193-44-9
• Molecular Weight: 407.251
• Mol File: 950193-44-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: FeC₅H₅C₅H₄C₂C₆H₄C₆H₄NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: FeC₅H₅C₅H₄C₂C₆H₄C₆H₄NO₂(950193-44-9)
• EPA Substance Registry System: FeC₅H₅C₅H₄C₂C₆H₄C₆H₄NO₂(950193-44-9)

Safety Data

• Hazardous Substances Data: 950193-44-9(Hazardous Substances Data)

Upstream product

• 1271-47-2 ferroceneacetylene 
• 29170-08-9 4-iodo-4'-nitrobiphenyl 

Downstream Products

• 950193-50-7 FeC₅H₅C₅H₄C₂C₆H₄C₆H₄NO₂Co₂(CO)6 

Relevant articles and documents

Studies on the synthesis, characterization and reactivity of new ferrocenylacetylenylbiphenyl derivatives

A series of ferrocenylacetylenylbiphenyl derivatives Fc-C{triple bond, long}C{single bond}R [R = C6H4{single bond}C6H5 (1), C6H4{single bond}C6H4{single bond}I (2), C6H4{single bond}C6H4{single bond}NO2 (3), C6H3(NO2){single bond}C6H4I (4)] and Fc-C{triple bond, long}C{single bond}R′{single bond}C{triple bond, long}C{single bond}R″ [R″ = Fc, R′ = C6H4{single bond}C6H4 (5), C6H3(NO2){single bond}C6H4 (6); R″ = C6H5, R′ = C6H4{single bond}C6H4 (7)] were synthesized from FcC{triple bond, long}CH and biphenyl iodides by the Castro-Stephens and Sonogashira coupling reactions, in which compounds 1, 2, 3, 4, 6 and 7 are new. Seven new complexes [Fc-C{triple bond, long}C{single bond}R][Co2(CO)6] [R = C6H4{single bond}C6H5 (8), C6H4{single bond}C6H4{single bond}I (9), C6H4{single bond}C6H4{single bond}NO2 (10), C6H3(NO2){single bond}C6H4I (11)] and [Fc-C{triple bond, long}C{single bond}R′{single bond}C{triple bond, long}C{single bond}R″] [Co2(CO)6]2 [R″ = Fc, R′ = C6H4{single bond}C6H4 (12), C6H3(NO2){single bond}C6H4 (13); R″ = C6H5, R′ = C6H4{single bond}C6H4 (14)] were obtained by the reaction of the ligands Fc-C{triple bond, long}C{single bond}R and Fc-C{triple bond, long}C{single bond}R′{single bond}C{triple bond, long}C{single bond}R″ with Co2(CO)8, respectively. Compounds 1-7 and their complexes 8-14 have been characterized by element analysis and spectroscopy, as well as by X-ray diffraction for 1, 4, 8, 9 and 11. The electrochemical data of compounds 1-12 have been obtained by cyclic voltammetry.