95064-54-3Relevant academic research and scientific papers
Preparation of imides via the palladium-catalyzed coupling reaction of organostannanes with methyl n-[methoxy(methylthio)methylene]carbamate
Orimoto, Kohei,Tomizawa, Takuhei,Namera, Yuki,Oyama, Harufumi,Niwa, Takashi,Nakada, Masahisa
, p. 827 - 840 (2013/05/08)
The preparation of imides via the palladium-catalyzed coupling reaction of organostannanes is described. The palladium-catalyzed coupling reaction of aryl-, heteroaryl-, and alkenyl(tributyl)stannanes with methyl N-[methoxy(methylthio)methylene]carbamate
Preparation of imides via the palladium-catalyzed coupling reaction of organoborons with methyl N -[methoxy(methylthio)methylene]carbamate as a one-carbon elongation reaction
Tomizawa, Takuhei,Orimoto, Kohei,Niwa, Takashi,Nakada, Masahisa
supporting information, p. 6294 - 6297 (2013/02/23)
The preparation of imides via the palladium-catalyzed coupling reaction as a one-carbon elongation reaction is described. The palladium-catalyzed coupling reaction of aryl-, alkyl-, and alkenylborons with N-[methoxy(methylthio) methylene]carbamate in the presence of Cu(I) thiophene-2-carboxylate (CuTC) affords imino ethers that are converted to the corresponding imides by acidic hydrolysis in high yield. The imino ethers are also useful for preparing the corresponding ester without using carbon monoxide.
