950747-03-2

Upstream product

• 950747-02-1 (S)-3-[(tert-butyldimethylsilyl)oxy]-6-[(4-methoxybenzyl)oxy]-1-hexyne 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 950747-16-7 (S)-6-((4-methoxybenzyl)oxy)hex-1-yn-3-ol 
• 950746-99-3 (S)-(+)-6-[(4-methoxybenzyl)oxy]-1-trimethylsilyl-1-hexyn-3-ol 
• 950746-98-2 6-[(4-methoxybenzyl)oxy]-1-trimethylsilyl-1-hexyn-3-one 
• 957300-51-5 (±)-6-(4-methoxybenzyloxy)-1-(trimethylsilyl)hex-1-yn-3-ol 

Downstream Products

• 950747-12-3 C₂₂H₄₃O₄Si₂SeC₆H₅ 

Relevant academic research and scientific papers

First total synthesis of modiolide A, based on the whole-cell yeast-catalyzed asymmetric reduction of a propargyl ketone

While the first total synthesis of modiolide A (1a), a 10-membered ring lactone with a marine-origin was achieved, an important chiral building block for constructing the chirality at C-4 in 1a, (S)-6-[(4-methoxybenzyl)oxy]-1-trimethylsilyl-1-hexyn-3-ol (