950839-30-2Relevant articles and documents
Nondoped deep-blue fluorescent organic electroluminescent device with CIEy = 0.06 and low efficiency roll-off based on carbazole/oxadiazole derivatives
Tan, Yu,Wang, Zhende,Wei, Chen,Liu, Zhiwei,Bian, Zuqiang,Huang, Chunhui
, p. 77 - 84 (2019/03/28)
Deep-blue organic light-emitting diodes (OLEDs) with the Commission Internationale de L'e’clairage (CIE) coordinates matching the European Broadcasting Union (EBU) standard blue CIE (x, y) coordinates of (0.15, 0.06) are very limited and in enormous deman
Bipolar molecules with high triplet energies: Synthesis, photophysical, and structural properties
Zheng, Yonghao,Batsanov, Andrei S.,Jankus, Vygintas,Dias, Fernando B.,Bryce, Martin R.,Monkman, Andrew P.
, p. 8300 - 8310 (2011/12/04)
This article sheds new light on the interplay of electronic and conformational effects in luminescent bipolar molecules. A series of carbazole/1,3,4-oxadiazole hybrid molecules is described in which the optoelectronic properties are systematically varied by substituent effects which tune the intramolecular torsion angles. The synthesis, photophysical properties, cyclic voltammetric data, X-ray crystal structures, and DFT calculations are presented. Excited state intramolecular charge transfer (ICT) is observed from the donor carbazole/2,7-dimethoxycarbazole to the acceptor phenyl/diphenyloxadiazole moieties. Introducing more bulky substituents onto the diphenyloxadiazole fragment systematically increases the singlet and triplet energy levels (ES and ET) and blue shifts the absorption and emission bands. The triplet excited state is located mostly on the oxadiazole unit. The introduction of 2,7-dimethoxy substituents onto the carbazole moiety lowers the value of ES, although ET is unaffected, which means that the singlet-triplet gap is reduced (for 7bE S - ET = 0.61 eV). A strategy has been established for achieving unusually high triplet levels for bipolar molecules (ET = 2.64-2.78 eV at 14 K) while at the same time limiting the increase in the singlet energy.