951008-01-8Relevant academic research and scientific papers
The catalytic asymmetric claisen rearrangement (CAC) in natural product synthesis: Synthetic studies toward (-)-ecklonialactone B
Wang, Qi,Millet, Agnès,Hiersemann, Martin
, p. 1683 - 1686 (2007)
A catalytic asymmetric Claisen rearrangement (CAC) in concert with a ring-closing metathesis (RCM) has been utilized in the enantioselective synthesis of the C10-C18 segment of ecklonialactone B. Georg Thieme Verlag Stuttgart.
Catalytic asymmetric claisen rearrangement of gosteli-type allyl vinyl ethers: Total synthesis of (-)-9,10-dihydroecklonialactone B
Becker, Julia,Butt, Lena,Von Kiedrowski, Valeska,Mischler, Elisabeth,Quentin, Florian,Hiersemann, Martin
, p. 3040 - 3051 (2014/05/06)
The enantioselective synthesis of (-)-9,10-dihydroecklonialactone B is described. The catalytic asymmetric Claisen rearrangement of a Gosteli-type allyl vinyl ether was utilized to afford an acyclic α-keto ester building block endowed with functionality a
