95110-65-9Relevant academic research and scientific papers
THE REACTION OF α,β-EPOXY SULFOXIDES WITH LITHIUM DIMETHYLCUPRATE GIVING ENOLATES: A NOVEL SYNTHESIS OF ALDOLS
Satoh, Tsuyoshi,Sugimoto, Atsushi,Itoh, Masayuki,Yamakawa, Koji
, p. 1083 - 1086 (2007/10/02)
The aldols 5 are synthesized from three components (1-chloroalkyl phenyl sulfoxide 1 and two kinds of carbonyl compounds 2 and 4) through α,β-epoxy sulfoxides 3 using lithium dimethylcuprate as an electron-transfer reagent.
α,β-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. I. A Novel Synthesis of Dialkyl Ketones and a Synthesis of Aldehydes from Ketones by One Carbon Elongation
Satoh, Tsuyoshi,Kaneko, Youhei,Izawa, Takao,Sakata, Kiichi,Yamakawa, Koji
, p. 1983 - 1990 (2007/10/02)
Treatment of α,β-epoxy sulfoxides, prepared from 1-chloroalkyl phenyl sulfoxides with ketones or aldehydes, with sodium benzeneselenolate gives dialkyl ketones or aldehydes in good yields under mild conditions.The mechanism of this reaction and an application of this process to a formal total synthesis of dihydrojasmone are described.
