951244-77-2Relevant academic research and scientific papers
Magnetic exchange coupling in chloride-bridged 5f-3d heterometallic complexes generated via insertion into a uranium(IV) dimethylpyrazolate dimer
Kozimor, Stosh A.,Bartlett, Bart M.,Rinehart, Jeffrey D.,Long, Jeffrey R.
, p. 10672 - 10674 (2008/02/13)
The homoleptic dimer complex [U(Me2Pz)4]2 (Me2Pz- = 3,5-dimethylpyrazolate) was obtained upon reacting UCl4 with KMe2Pz in THF, followed by extraction into toluene. The structure of the dimer consists of two UIV centers, each coordinated in a pseudo trigonal bipyramidal geometry, connected through two bridging Me2Pz- ligands. Bases are capable of cleaving the dimer; for example, reaction with THF affords the mononuclear complex (Me2Pz)4U(THF). More importantly, the dimer can be cleaved via insertion of terminal chloride ligands, such that reactions with (cyclam)MCl2 (M = Ni, Cu, Zn; cyclam = 1,4,8,11-tetraazacyclotetradecane) in dichloromethane generate the linear, chloride-bridged clusters (cyclam)M[(μ-Cl)U(Me2Pz)4]2. Variable-temperature magnetic susceptibility data were collected for all three clusters to probe any possible magnetic exchange coupling. The data for the cluster centered by an S = 0 ZnII ion exhibit behavior typical of UIV complexes, with χMT decreasing steadily as the temperature drops. Data for the CuU2 cluster show a parallel variance with temperature, indicating the absence of any magnetic exchange coupling. In contrast, subtracting the ZnU2 data from the NiU2 data exposes a rise in χMT with decreasing temperature, suggesting weak ferromagnetic coupling between the NiII (S = 1) and UIV centers. Employing a simple spin-only exchange model, a lower bound for the coupling constant was estimated at J = 2.3 cm-1. Consistent with a simple superexchange mechanism for the coupling, density functional theory calculations performed on a [(Me2Pz)4UCl]- fragment of the cluster show the spin to reside in 5fxyz and 5fz(x2-y2) orbitals, exhibiting δ symmetry with respect to the U-Cl bond. Low-temperature magnetization data collected for NiU2 suggest the presence of a large axial zero-field splitting; however, ac magnetic susceptibility experiments gave no indication of single-molecule magnet behavior. Copyright
