952117-47-4

Upstream product

• 75-65-0 tert-butyl alcohol 
• 79-37-8 oxalyl dichloride 
• 56442-43-4 4-(benzyloxy)benzamide 

Downstream Products

• 952117-19-0 (R)-(+)-tert-butyl [1-(4-benzyloxy-N-(but-3-en-1-yl)benzamido)but-3-en-2-yl]carbamate 
• 952117-14-5 (R)-(+)-tert-butyl [1-(N-benzyl-(4-benzyloxybenzamido))but-3-en-2-yl]carbamate 

Relevant academic research and scientific papers

Rh(III)-catalyzed annulation of BOC-protected benzamides with diazo compounds: Approach to isocoumarins

A mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C?C/C?O bond formation has been explored. In the presence of [Cp*RhCl2]2, AgSbF6 and Cs2CO3, Boc-protected benzamides can be effectively annulated to yield isocoumarins in 0.5–2 h.

Dynamic kinetic asymmetric allylic amination and acyl migration of vinyl aziridines with imido carboxylates

(Chemical Equation Presented) An atom-economical method has been developed for the preparation of chiral vicinal diamines through a dynamic kinetic asymmetric allylic amination and acyl-group migration of vinyl aziridines with imido carboxylates. Application of the asymmetric transformation enabled the concise synthesis of the azepane core 1 of (+)-balanol and its syn analogue.