95234-65-4Relevant academic research and scientific papers
REACTIONS OF AZIRINES WITH SULFUR NUCLEOPHILES. 4. TREATMENT OF 2H-AZIRINE WITH MERCAPTOSUBSTITUTED ACIDS. REACTIONS OF AZIRIDINYL ALKYL SULFIDES WITH CARBOXYLIC ACIDS AND ACYL CHLORIDE DERIVATIVES
El'kinson, R.S.,Eremeev, A.V.
, p. 161 - 166 (2007/10/02)
Treatment of 2H-azirines with mercaptosubstituted acids and their derivatives leads to β-ketoamides and 2-aziridinyl alkyl sulfides, respectively. 2-Aziridinyl alkyl sulfides, in turn, react with carboxylic acids to give β-ketoamides and substituted ethanethiol derivatives.Acylation of 2-aziridinyl alkyl sulfides with acyl halides generates a variety of products, depending on the reaction conditions; either products derived from cleavage and isomerization of the aziridinyl ring or (1-acylaziridinyl-2) alkyl sulfides are obtained.
REACTIONS OF AZIRINES WITH SULFUR NUCLEOPHILES. 2. REACTIONS OF 2H-AZIRINE WITH β,γ-DIHYDROXYTHIOLS AND β-DITHIOLS. A NEW ROUTE TO THE SYNTHESIS OF CYCLIC SULFIDES
El'kinson, R. S.,Eremeev, A. V.,Liepin'sh, E. E.
, p. 521 - 525 (2007/10/02)
The reaction of 2H-azirine with a number of dihydroxy thiols and dithiols leads to aziridin-2-yl alkyl sulfides.The latter readily isomerize to cyclic sulfides the size of the ring of which is determined by the length of the alkyl sulfide chain.
