95280-64-1

Upstream product

• 108-31-6 maleic anhydride 
• 2811-50-9 7-methoxy-4-vinyl-1,2-dihydronaphthalene 
• 27060-75-9 4-bromo-3-methylanisole 
• 7507-86-0 2-bromo-5-methoxy-benzaldehyde 
• 40154-05-0 2-(6-methoxy-3,4-dihydro-1-naphthalen-1-yl)-ethan-1-ol 
• 1078-19-9 6-methoxy-3,4-dihydro-1(2H)-naphthalenone 
• 158237-98-0 1,2-dihydro-4-ethynyl-7-methoxynaphthalene 
• 681427-54-3 1-(5-methoxy-2-((trimethylsilyl)ethynyl)phenyl)but-3-en-1-ol 
• 681427-53-2 5-methoxy-2-[2-(trimethylsilyl)ethynyl]benzaldehyde 
• 681427-55-4 2-(but-3-enyl)-1-ethynyl4-methoxybenzene 
• 681427-75-8 1-bromo-2-dibromomethyl-4-methoxybenzene 

Relevant academic research and scientific papers

Tandem Enyne Metathesis-Diels-Alder Reaction for Construction of Natural Product Frameworks

Enynes connected through aromatic rings are used as substrates for metathesis reactions. The reactivity of three ruthenium carbene complexes is compared. The resulting 1,3-dienes are suitable precursors of polycyclic structures via a Diels-Alder process.

Catalysis of a Diels-Alder reaction by amidinium ions

Amidines and guanidines are important functional groups in molecular recognition and host-guest chemistry. Here it is shown that lipophilic amidinium ions catalyze a cycloaddition reaction representing the key step of the Quinkert-Dane estrone synthesis.