953-21-9

Basic information

• Product Name: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline
• CAS NO: 953-21-9
• Molecular Formula: C₁₅H₁₃N
• Molecular Weight: 207.2704
• Mol File: 953-21-9.mol
• Article Data: 108

Chemical Properties

• Boiling Point: 350.5°C at 760 mmHg
• Flash Point: 158°C
• Density: 0.93g/cm³
• Vapor Pressure: 8.87E-05mmHg at 25°C
• Refractive Index: 1.54
• CAS DataBase Reference: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline(953-21-9)
• EPA Substance Registry System: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline(953-21-9)

Safety Data

• Hazardous Substances Data: 953-21-9(Hazardous Substances Data)

Upstream product

• 37056-75-0 cinnamaldehyde-(N-phenyl oxime ) 
• 62-53-3 aniline 
• 104-55-2 3-phenyl-propenal 
• 1142-24-1 N-cinnamylbenzenamine 
• 2325-27-1 N-phenyltriphenyliminophosphorane 
• 14371-10-9 (E)-3-phenylpropenal 
• 104-54-1 3-Phenylpropenol 
• 91-22-5 quinoline 
• 106-46-7 para-dichlorobenzene 
• 1152-13-2 5-phenyl-3-phenylimino-dihydro-furan-2-one 
• 541-73-1 1,3-Dichlorobenzene 
• 17408-56-9 3-anilino-5-phenyl-5H-furan-2-one 
• 95-50-1 1,2-dichloro-benzene 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Downstream Products

• 14371-10-9 (E)-3-phenylpropenal 
• 37902-58-2 3-phenylcarbamoylacrylic acid 
• 91462-38-3 1,4-diphenyl-3,4-dihydro-1H-pyridin-2-one 
• 14568-89-9 2-cinnamyl-2-(phenylamino)acetonitrile 
• 28010-12-0 5-phenylpenta-2,4-dienoic acid 
• 612-96-4 2-Phenylquinoline 
• 37975-95-4 3,6-diphenyl-2-styryl-2,3-dihydro-[1,3,5]thiadiazin-4-one 
• 86449-85-6 4-cinnamyl-1-phenyl-2-azetidinone 
• 138991-02-3 1,3,4-Triphenyl-3,4-dihydro-2(1H)pyridone 
• 85380-78-5 4-Chloro-N-(3-methyl-2-oxo-1,4-diphenyl-1,2,3,4-tetrahydro-pyridin-3-yl)-benzamide 
• 86129-95-5 3,3-Dichloro-3,4-dihydro-N,4-diphenyl-2-pyridone 
• 145825-99-6 1-Furan-2-yl-2-[4-phenyl-4H-[1,3]dithiin-(2E)-ylidene]-ethanone 
• 85380-88-7 N-(3-Methyl-2-oxo-1,4-diphenyl-1,2,3,4-tetrahydro-pyridin-3-yl)-2-phenyl-acetamide 
• 118714-23-1 cinnamylideneaniline hydrochloride 

Relevant articles and documents

Cobalt-Catalyzed Deoxygenative Hydroboration of Nitro Compounds and Applications to One-Pot Synthesis of Aldimines and Amides

The commercially available and bench-stable Co(acac)2 ligated with bis[(2-diphenylphosphino)phenyl] ether (dpephos) was employed for selective room temperature hydroboration of nitro compounds with HBPin (TOF up to 4615 h?1), tolerating halide, hydroxy, amino, ether, ester, lactone, amide and heteroaromatic functionalities. These reactions offered a direct access to a variety of N-borylamines RN(H)BPin, which were in situ treated with aldehydes and carboxylic acids to produce a series of aldimines and secondary carboxamides without the need for dehydrating and/or coupling reagents. Combination of these transformations in a sequential one-pot manner allowed for direct and selective synthesis of aldimines and secondary carboxamides from readily available and inexpensive nitro compounds.

A Sustainable Palladium-Intercalated Montmorillonite Clay Catalytic System for Imine Hydrogenation under Mild Conditions

A series of palladium nanoparticles (Pd NPs) intercalated montmorillonite clay catalysts is reported for hydrogenation of 3-diphenyl prop-2-en-1-imine under mild reaction conditions. Pd/clay catalyst was prepared by a simple wet-impregnation method, and t

Synthesis of β-Phosphinolactams from Phosphenes and Imines

Various cis-β-phosphinolactams are synthesized stereoselectively for the first time from imines and diazo(aryl)methyl(diaryl)phosphine oxides under microwave irradiation. Diazo(aryl)methyl(diaryl)phosphine oxides first undergo the Wolf rearrangement to generate phosphenes. Imines nucleophilically attack the phosphenes followed by an intramolecular nucleophilic addition via less steric transition states to give final cis-β-phosphinolactams. C-Styrylimines generally give rise to β-phosphinolactams in higher yields than C-arylimines. The stereoselectivity and proposed mechanism are rationalized by DFT theoretical calculation.