95308-77-3Relevant academic research and scientific papers
The Unusual Anodic Reactivity of Tertiary Enamines in the Presence of Base: the Effect of the Nature of the Base on the Product Distribution
Cariou, Michel,Simonet, Jacques
, p. 1146 - 1147 (1984)
The anodic oxidation of aromatic N-methyl-N-phenylenamines leads to dimers and trimers in the presence of K2CO3, whereas in the presence of 2,6-lutidine demethylation occurs and, in one case, this is subsequent to cyclisation and results in a new 3H-indole.
Enamines et enediamines: synthese et oxydation anodique. Application a la formation de nouveaux heterocycles
Cariou, Michel,Carlier, Roger,Simonet, Jacques
, p. 781 - 792 (2007/10/02)
The anodic oxidation of certain tertiary enamines and enediamines is particularly sensitive to the medium effect: specific action of bases leading to either dimers or trimers, or to the formation of a new 3 H-indole (case of enamines); reaction with moisture in the solvent allowing the obtention of indolooxazolidines (case of enediamines).The reactivity of the oxidized forms of the substrates is discussed as a function of the nature of the electrolysis medium and the structure of the products amenable to electrolysis.
