95338-10-6Relevant academic research and scientific papers
Stereocontrolled synthesis of all eight stereoisomers of the putative anti-androgen cyoctol
Mulzer, Johann,Kaselow, Ulrich,Graske, Klaus-Dieter,Kühne, Holger,Sieg, Andreas,Martin, Harry J.
, p. 9599 - 9614 (2007/10/03)
All eight stereoisomers (1-4 and enantiomers) of the putative anti-androgen cyoctol have been synthesized along stereochemically unambiguous routes. The biological tests of all isomers indicated that cyoctol is not an anti-androgen, contrary to the patent literature. All eight stereoisomers of the putative anti-androgen cyoctol have been prepared and tested biologically.
A New Catalytic Asymmetric Approach to Polyfunctional Aldol Products Mediated by Zinc Organometallics.
Knochel, Paul,Brieden, Walter,Rozema, Michael J.,Eisenberg, Christina
, p. 5881 - 5884 (2007/10/02)
The catalytic asymmetric addition of functionalized dialkylzincs to β-alkoxyaldehydes provides after a short sequence of functional group interconversions aldol products in 40-99 percentee.Their stereoselective transformation to either syn- or anti-1,3-di
SYNTHESIS OF ALL OF THE FOUR ENERGETICALLY POSSIBLE STEREOISOMERS OF 7-ETHYL-2-METHYL-1,6-DIOXASPIRODECANE; A PHEROMONE PRODUCED BY BEES PARAVESPURA VULGARIS L. AND ANDRENA HAEMORRHOA F.
Mori, Kenji,Ikunaka, Masaya
, p. 3471 - 3480 (2007/10/02)
All of the four energetically possible stereoisomers of 7-ethyl-2-methyl-1,6-dioxaspirodecane were synthesized starting from ethyl (S)-lactate and dimethyl (S)-malate or methyl (R)-β-hydroxy-valerate employing dianion alkylation as the key-step.
