95391-85-8Relevant academic research and scientific papers
A facile stereoselective synthesis of (E)-1-arylseleno-2- arylsulfanylethenes via hydrozirconation of arylselenoethynes
Cai, Ming-Zhong,Jiang, Min-Hua,Li, Hai-Gen
, p. 702 - 704 (2007/10/03)
Hydrozirconation of arylselenoethynes 1 gave (E)-2- arylselenovinylzirconium(IV) complexes 2, which reacted with arylsulfenyl chlorides 3 stereoselectively to afford (E)-1-arylseleno-2-arylsulfanylethenes 4 in good yields. (E)-1-Arylseleno-2-arylsulfanyle
Synthesis of Vinyl Selenides or Sulfides and Ketene Selenoacetals or Thioacetals by Nickel(II) Vinylation of Sodium Benzeneselenolate or Benzenethiolate
Cristau, H. J.,Chabaud, B.,Labaudiniere, R.,Christol, H.
, p. 875 - 878 (2007/10/02)
The substitution of bromine atom on a double bond by benzeneselenolate or benzenethiolate anions is catalyzed by the bis(pyridine)nickel bromide complex.Various alkenyl selenides or sulfides and seleno- or thio acetals are prepared in good to excellent yi
NEW SYNTHESIS OF VINYL SELENIDES NUCLEOPHILIC SUBSTITUTIONS OF UNACTIVATED VINYL HALIDES BY SELENIDE ANIONS
Tiecco, M.,Testaferri, L.,Tingoli, M.,Chianelli, D.,Montanucci, M.
, p. 4975 - 4978 (2007/10/02)
Alkyl and aryl selenide anions react with unactivated vinyl halides, in dipolar aprotic solvents, to give alkyl or aryl vinyl selenides in good yields.These reactions are stereospecific and occur with retention of configuration.
