95416-62-9Relevant academic research and scientific papers
2-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated ketones under ligand-free and neutral conditions
Zhang, Lei,Xie, Xiaomin,Fu, Lei,Zhang, Zhaoguo
, p. 3434 - 3437 (2013/06/26)
A simple and efficient Ru-catalyzed conjugate addition reaction of arylboronic acids to α,β-unsaturated ketones under neutral conditions without any additional ligands has been developed. This Ru(II)-catalytic system both fulfilled the inhibition of the β-hydride elimination in the catalytic cycle and minimized the protonolysis of arylboronic acids.
C-X (X=Br, I) bond-tolerant aerobic oxidative cross-coupling: A strategy to selectively construct β-aryl ketones and aldehydes
Chen, Mao,Wang, Jie,Chai, Ziyi,You, Cai,Lei, Aiwen
supporting information; experimental part, p. 341 - 346 (2012/05/04)
Using moelcular oxygen as the terminal oxidant, various aryl halide-containing β-aryl ketones and aldehydes can be synthesized directly from readily available allyic alcohols and boronic acids via palladium-catalyzed oxidative cross-coupling reactions. The dual roles of copper, including electron-carrier and Lewis acid functions, are supposed to be critical for the high reactivity and selectivity of this aerobic oxidative coupling transformation. Copyright
Palladium-catalysed Vinylation of Organic Halides under Solid-Liquid Phase Transfer Conditions
Jeffery, Tuyet
, p. 1287 - 1289 (2007/10/02)
Heck-type reactions involving organic halides proceed readily at or near room temperature when performed under solid-liquid phase transfer conditions.
