95416-99-2

Basic information

• Product Name: 2-Thiabicyclo[2.2.1]hept-5-ene, 3-phenyl-, endo-
• CAS NO: 95416-99-2
• Molecular Formula: C12H12S
• Molecular Weight: 188.293
• Mol File: 95416-99-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Thiabicyclo[2.2.1]hept-5-ene, 3-phenyl-, endo-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Thiabicyclo[2.2.1]hept-5-ene, 3-phenyl-, endo-(95416-99-2)
• EPA Substance Registry System: 2-Thiabicyclo[2.2.1]hept-5-ene, 3-phenyl-, endo-(95416-99-2)

Safety Data

• Hazardous Substances Data: 95416-99-2(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 2408-88-0 2-benzylsulfanyl-1-phenylethanone 
• 542-92-7 cyclopenta-1,3-diene 
• 100-53-8 phenylmethanethiol 
• 38225-20-6 α-(trimethylsilyl)benzylthiol 
• 6725-34-4 thiobenzaldehyde 
• 118201-67-5 3-exo-phenyl-3-endo-trimethylsilyl-2-thiabicyclo<2.2.1>hept-5-ene 
• 98909-99-0 [(4-Chloro-phenyldisulfanyl)-phenyl-methyl]-trimethyl-silane 

Relevant articles and documents

Continuous Flow Synthesis of 2H-Thiopyrans via thia-Diels–Alder Reactions of Photochemically Generated Thioaldehydes

Herein, we report a novel protocol for the photochemical generation of thioaldehydes in a continuous flow process which were in situ reacted with electron rich 1,3-butadienes in thia-Diels–Alder reactions. A broad range of 3,6-dihydro-2H-thiopyrans were formed as products in much higher yields and productivities as compared to classical batch processes. Moreover, greatly reduced reaction times and a facile large-scale preparation of products were achieved by fully exploiting the advantages of continuous flow technology.

STEREOCHEMISTRY OF PROTIODESILYLATION OF 3-TRIMETHYLSILYL-2-THIABICYCLOHEPTENES, HEPTANES AND DERIVATIVES.

Some 3-trimethylsilyl-2-thiabicycloheptenes and heptanes of known configuration were protiodesilylated and the stereochemistry of the reaction was studied.Evidences for a carbanionic intermediate as well as the pivotal role played by the metal coun

Transformation of Thiosulphonates into α-Sulphonyldisulphides, a New Class of Thioaldehyde Precursors

Toluene-p-thiosulphonates, RCH2SSO2Tol (1) where R is an electron-withdrawing group, are transformed readily into α-sulphonyldisulphides (2) which, with triethylamine, undergo fragmentation-elimination to give 2 moles of thioaldehydes, RCHS.