954374-96-0

Basic information

• Product Name: C₂₉H₃₀NO₇Br
• Synonyms: C₂₉H₃₀NO₇Br
• CAS NO: 954374-96-0
• Molecular Weight: 584.464
• Mol File: 954374-96-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₉H₃₀NO₇Br(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₉H₃₀NO₇Br(954374-96-0)
• EPA Substance Registry System: C₂₉H₃₀NO₇Br(954374-96-0)

Safety Data

• Hazardous Substances Data: 954374-96-0(Hazardous Substances Data)

Upstream product

• 623-47-2 propynoic acid ethyl ester 
• 954374-78-8 ethyl (E)-3-(4-bromo-2-formylphenoxy)acrylate 
• 100-52-7 benzaldehyde 
• 106-49-0 p-toluidine 

Downstream Products

• 954375-13-4 C₂₄H₂₄NO₅Br 

Relevant articles and documents

Domino reaction of 3-(2-formylphenoxy)propenoates and amines: A novel synthesis of 1,4-dihydropyridines from salicaldehydes, ethyl propiolate, and amines

(Chemical Equation Presented) A novel synthesis of Hantzsch-type N-substituted 1,4-dihydropyridines from salicaldehydes, ethyl propiolate, and amines has been developed. Salicaldehydes were treated with ethyl propiolate in the presence of N-methyimorpholine to give ethyl 3-(2-formylphenoxy)propenoates. Three equivalents of ethyl 3-(2-formylphenoxy)propenoates reacted with 1 equiv of amines under trifluoroacetic acid (TFA) catalyst to furnish the corresponding N-substituted 1,4-dihydropyridines in good to excellent yields, recovering the starting material salicaldehydes. A possible mechanism for the domino process was proposed. Furthermore, the products can be easily derived via further transformations and three of them exhibited strong fluorescence (Φf = 0.36-0.63).