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CAS

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95475-52-8

cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranoside is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 95475-52-8 Structure

  • Basic information

    1. Product Name: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranoside
    2. Synonyms: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranoside
    3. CAS NO:95475-52-8
    4. Molecular Formula:
    5. Molecular Weight: 498.312
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 95475-52-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranoside(CAS DataBase Reference)
    10. NIST Chemistry Reference: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranoside(95475-52-8)
    11. EPA Substance Registry System: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranoside(95475-52-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 95475-52-8(Hazardous Substances Data)

95475-52-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 95475-52-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,5,4,7 and 5 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 95475-52:
(7*9)+(6*5)+(5*4)+(4*7)+(3*5)+(2*5)+(1*2)=168
168 % 10 = 8
So 95475-52-8 is a valid CAS Registry Number.

95475-52-8Downstream Products

95475-52-8Relevant articles and documents

A Rapid and Diastereoselective Synthesis of 2-Deoxy-2-iodo-α-glycosides and its Mechanism for Diastereoselectivity

Yuan, Wenjiao,Liu, Yali,Li, Chunbao

supporting information, p. 1975 - 1978 (2017/09/13)

Reductive deiodination of 2-deoxy-2-iodo-glycoside is an efficient and practical approach for the synthesis of 2-deoxyglycosides, which are moieties of bioactive compounds. However, inseparable diastereoisomers are usually formed in the preparation of 2-deoxy-2-iodo-glycosides via glycosylation of glycals with alcohols using current methods. To overcome this problem, a rapid and diastereoselective transformation of glycals and alcohols into 2-deoxy-2-iodo-α-glycosides enabled by I 2 /PhI(OAc) 2 has been developed. 14 glycals, derived from 13 monosaccharides and one disaccharide, diastereoselectively yielded α-glycosides. Only in two cases the diastereoselectivity of the glycosylation was poor. The yields of glycosylation range from 73% to 95%, and the reactions are finished in only five minutes. Investigations for better diastereoselectivity by comparing I 2 /Ph(OAc) 2 - with I 2 /Cu(OAc) 2 -mediated glycosylations using UV analysis have been conducted.

Convertible formation of different glycoside using molecular iodine

Saeeng, Rungnapha,Sirion, Uthaiwan,Sirichan, Yada,Trakulsujaritchok, Thanida,Sahakitpichan, Poolsak

experimental part, p. 2569 - 2580 (2011/04/22)

The observation of convertible formation between 2-deoxy-2-iodo-O- glycosides and 2,3-unsaturated glycoside was described. The selective formation of 2-deoxy-2-iodo-O-glycosides was found from the reaction of D-glucal with iodine in the excess alcohol acceptor or the addition of ceric ammonium nitrate as additive while the addition of a stoichiometric amount of alcohol in solvent favored 2,3-unsaturated glycosides formation. The Japan Institute of Heterocyclic Chemistry.

An efficient method for the selective synthesis of 2-deoxy-2-iodo- glycosides by O-glycosidation of d-glucal using I2-Cu(OAc) 2

Sirion, Uthaiwan,Purintawarrakun, Sittidate,Sahakitpichan, Poolsak,Saeeng, Rungnapha

experimental part, p. 2401 - 2407 (2010/11/18)

An efficient and convenient method for the synthesis of 2-deoxy-2-iodo-O-glycosides from tri-O-acetyl-d-glucal with various alcohols by using I2-Cu(OAc)2 is described. The 21 examples of corresponding glycosides were obtained in high

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