95497-10-2Relevant academic research and scientific papers
Silylamines in Organic Synthesis. Facile Synthetic Routes to Unsaturated Protected Primary Amines.
Corriu, Robert J. P.,Huynh, Vilam,Iqbal, Javed,Moreau, Joel J. E.,Vernhet, Claude
, p. 6231 - 6244 (2007/10/02)
The reactions of lithium N,N-bis(trimethylsilyl)aminomethyl acetylide with electrophilic reagents offered a short preparation of substituted and functional propargyl amines.These are shown to be useful precursors of various saturated protected primary amines.Addition reactions to the carbon-carbon triple bond or isomerisation reactions gave rise to allylic, dienic and α-allenic amines. Keywords: Silylamines; propargylamines, α-allenylamines; N,N-bis(silyl)dienamines.
USES OF SI-N BONDS IN SYNTHESIS: EASY ROUTES TO FUNCTIONAL PROTECTED PRIMARY AMINES FROM PROPARGYLIC SILYLAMINES
Corriu, Robert J.P.,Huynh, Vilam,Iqbal, Javed,Moreau, Joel J.E.
, p. C61 - C64 (2007/10/02)
The readily obtained N,N-bis(trimethylsilyl)-propargylic amines are shown to be useful precursors of various functional protected primary amines.It readily gives rise to N,N-bis(trimethylsilyl)dienamines, 2-aza-1,3,5-hexatrienes, α-allenic amines, substit
