91375-43-8Relevant academic research and scientific papers
Silylamines in Organic Synthesis. Facile Synthetic Routes to Unsaturated Protected Primary Amines.
Corriu, Robert J. P.,Huynh, Vilam,Iqbal, Javed,Moreau, Joel J. E.,Vernhet, Claude
, p. 6231 - 6244 (2007/10/02)
The reactions of lithium N,N-bis(trimethylsilyl)aminomethyl acetylide with electrophilic reagents offered a short preparation of substituted and functional propargyl amines.These are shown to be useful precursors of various saturated protected primary amines.Addition reactions to the carbon-carbon triple bond or isomerisation reactions gave rise to allylic, dienic and α-allenic amines. Keywords: Silylamines; propargylamines, α-allenylamines; N,N-bis(silyl)dienamines.
