95497-16-8

Upstream product

• 95497-12-4 Acetic acid 4-(1,1,1,3,3,3-hexamethyl-disilazan-2-yl)-1-phenyl-but-2-ynyl ester 
• 91375-24-5 lithium N,N-bis(trimethylsilyl)aminomethyl acetylide 
• 91375-25-6 1,1,1,3,3,3-hexamethyl-2-(prop-2-ynyl)disilazane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

USES OF SI-N BONDS IN SYNTHESIS: EASY ROUTES TO FUNCTIONAL PROTECTED PRIMARY AMINES FROM PROPARGYLIC SILYLAMINES

The readily obtained N,N-bis(trimethylsilyl)-propargylic amines are shown to be useful precursors of various functional protected primary amines.It readily gives rise to N,N-bis(trimethylsilyl)dienamines, 2-aza-1,3,5-hexatrienes, α-allenic amines, substit

Silylamines in Organic Synthesis. Facile Synthetic Routes to Unsaturated Protected Primary Amines.

The reactions of lithium N,N-bis(trimethylsilyl)aminomethyl acetylide with electrophilic reagents offered a short preparation of substituted and functional propargyl amines.These are shown to be useful precursors of various saturated protected primary amines.Addition reactions to the carbon-carbon triple bond or isomerisation reactions gave rise to allylic, dienic and α-allenic amines. Keywords: Silylamines; propargylamines, α-allenylamines; N,N-bis(silyl)dienamines.