95514-22-0Relevant articles and documents
Ring Transformation Equilibrium (Bond Switch) in the 5-(2-Aminovinyl)isothiazole System via Hypervalent Sulfurane. Synthesis, Structure Determination, and Kinetic Study
Akiba, Kin-ya,Kashiwagi, Kohichi,Ohyama, Yoshihiko,Yamamoto, Yoshuke,Ohkata, Katsuo
, p. 2721 - 2730 (2007/10/02)
Reaction of 3-aryl-5-methylisothiazoles (4) with aromatic nitriles afforded the adducts 3, 5-(2-amino-2-arylvinyl)-3-arylisothiazole derivatives, in the presence of LDA.By employing p-chlorobenzonitrile-15N, the presence of ring transformation from one is