95578-28-2Relevant academic research and scientific papers
The Stereocontrolled Synthesis of a 2,3,3-Trisubstituted Cyclohexanone Involving Hydroxylactonisation of a Tertiary Amide
Cairns, Peter M.,Howes, Colin,Jenkins, Paul R.
, p. 627 - 632 (2007/10/02)
A new method for the stereocontrolled synthesis of 2,3,3-trisubstituted cyclohexanones is reported which involves the first example of hydroxylactonisation of a γ,δ-unsaturated tertiary amide followed by reductive cleavage of the lactone to produce the su
A Stereocontrolled Synthesis and X-Ray Crystal Structure of a 2,3,3-Trisubstituted Cyclohexanone
Cairns, Peter M.,Howes, Colin,Jenkins, Paul R.,Russell, David R.,Sherry, Lesly
, p. 1487 - 1488 (2007/10/02)
A γ,δ-unsaturated amide, prepared by an amide acetal Claisen rearrangement, has been subjected to hydroxy-lactonisation, and reductive cleavage of the corresponding keto-lactone with aluminium amalgam has led to a trisubstituted cyclohexanone derivative w
