957-82-4Relevant academic research and scientific papers
Bay-Region Annulative π-Extension of o-Iodobiphenyls with Aliphatic Anhydrides Catalyzed by Pd(OAc)2
Huang, Lin,Chen, Li-Ping,Du, Yu,Fang, Mao-Ying,Wang, Bi-Qin,Feng, Chun,Xiang, Shi-Kai
supporting information, p. 7535 - 7539 (2021/10/12)
Bay-region annulative π-extension of o-iodobiphenyls with aliphatic anhydrides was developed. Many o-iodobiphenyls and aliphatic anhydrides can react well under the optimized conditions. A lot of phenanthrol derivatives can be efficiently prepared by this approach. The control experiments support that dibenzopalladacyclopentadienes may be the reaction intermediates.
Light-induced carbocyclization of iodoalkenes
Campos-Gómez, Esther,Campos, Pedro J.,González, Héctor F.,Rodríguez, Miguel A.
experimental part, p. 4292 - 4295 (2012/07/16)
The direct irradiation of iodoalkenes leads to the formation of carbon-centered radical by homolysis of the C-I bond. The photoreaction is used in cyclizations with formation of six membered rings.
