957-94-8

Upstream product

• 138479-52-4 11H-indolo<1,2-b>indazol-11-one 
• 124-38-9 carbon dioxide 
• 7788-69-4 1-phenyl-1H-indazole 
• 446-52-6 2-Fluorobenzaldehyde 
• 271-44-3 benzimidazole 
• 138479-51-3 2-(indazol-2'-yl)benzaldehyde 

Downstream Products

• 1632155-75-9 methyl 2-(1H-indazol-1-yl)benzoate 

Relevant academic research and scientific papers

Ruthenium-catalyzed c-h silylation of 1-arylpyrazole derivatives and fluoride-mediated carboxylation: Use of two nitrogen atoms of the pyrazole Group

Carboxylation of 1-arylpyrazole derivatives was developed using a ruthenium-catalyzed ortho silylation in conjunction with fluoride-mediated carboxylation with carbon dioxide. The two nitrogen atoms of pyrazole play crucial roles in promoting ortho silylation via the formation of a five-membered ruthenacycle and in accelerating aryl anion formation by lowering the electron density of the aromatic ring. Georg Thieme Verlag Stuttgart New York.

Cyclization Reactions in Azole Chemistry: The Reaction of Some Azoles with o-Fluoroacetophenone, o-Fluorobenzaldehyde and o-Fluorobenzophenone

The reactions of some azoles with o-fluoro-acetophenone, -benzaldehyde and -benzophenone in dimethyl sulfoxide solution in the presence of anhydrous potassium carbonate have been investigated.In addition to the expected substitution products, cyclization