95705-20-7

Basic information

• Product Name: 1,3,5-tris(benzyloxy)-1,3,5-triazinane-2,4,6-trione
• Synonyms: 1,3,5-tris(benzyloxy)-1,3,5-triazinane-2,4,6-trione;1,3,5-Tribenzyloxy-1,3,5-triazinane-2,4,6-trione
• CAS NO: 95705-20-7
• Molecular Formula: C₂₄H₂₁N₃O₆
• Molecular Weight: 447.44004
• Mol File: 95705-20-7.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,3,5-tris(benzyloxy)-1,3,5-triazinane-2,4,6-trione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tris(benzyloxy)-1,3,5-triazinane-2,4,6-trione(95705-20-7)
• EPA Substance Registry System: 1,3,5-tris(benzyloxy)-1,3,5-triazinane-2,4,6-trione(95705-20-7)

Safety Data

• Hazardous Substances Data: 95705-20-7(Hazardous Substances Data)

Usage

General Description

1,3,5-tris(benzyloxy)-1,3,5-triazinane-2,4,6-trione is a chemical compound with the molecular formula C27H21N3O6. It is a triazine-based compound, featuring three benzyloxy groups attached to the nitrogen atoms of the triazine ring. This chemical is a white to off-white powder, and it is mainly used as a crosslinking agent in the production of epoxy resins and other polymers. It is also utilized as a building block in organic synthesis and pharmaceutical research. Additionally, this compound has shown potential antioxidant and antitumor properties in preliminary studies. While it is not commonly found in consumer products, it is an important intermediate for the synthesis of other organic compounds and materials.

Upstream product

• 301651-11-6 N-benzyloxy-1H-benzotriazole-1-carboxamide 
• 622-33-3 N-benzyloxyamine 
• 530-62-1 1,1'-carbonyldiimidazole 
• 102-09-0 bis(phenyl) carbonate 
• 2687-43-6 O-benzylhydoxylamine hydrochloride 
• 730-18-7 N-benzyloxycarbamic acid phenyl ester 
• 1885-14-9 phenyl chloroformate 
• 92289-72-0 imidazole-1-carboxylic acid benzyloxyamide 

Downstream Products

• 143435-52-3 1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione 

Relevant articles and documents

PROCESS FOR PRODUCTION OF N,N';N''-TRISUBSTITUTED ISOCYANURIC ACIDS

A process produces an N,N',N"-trisubstituted isocyanuric acid represented by following Formula (4): wherein R is a hydroxyl-protecting group, by heating an N-substituted carbamic acid derivative represented by following Formula (1): wherein R has the same

Development of an efficient method for preparation of 1,3,5- trihydroxyisocyanuric acid (THICA) and its use as aerobic oxidation catalyst

1,3,5-Trihydroxyisocyanuric acid (THICA), which serves as an efficient radical-producing catalyst from hydrocarbons, was successfully prepared by two methods. The reaction of O-benzylhydroxyamine with phenyl chloroformate gave formbenzyloxycarbamic acid phenyl ester of which subsequent treatment with dimethylaminopyridine (DMAP) produced 1,3,5-tribenzyloxyisocyanurate leading to THICA by hydrogenation with H2 on Pd/C. The other method involved the direct synthesis of 1,3,5-tribenzyloxyisocyanurate from O-benzylhydroxyamine and diphenyl carbonate. The aerobic oxidation of p-methylanisole catalyzed using THICA as a key catalyst afforded p-anisic acid in almost quantitative yield (>99%).

Oxidation of substituted toluenes with molecular oxygen in the presence of N,N′,N″-Trihydroxyisocyanuric acid as a key catalyst

N,N′,N″-Trihydroxyisocianuric acid (THICA) was found to be a very efficient catalyst for the oxidation of alkylbenzenes with dioxygen. Thus, a variety of meta- and para-substituted toluenes bearing an electron-withdrawing substituent such as cyanotoluene, chlorotoluene, and toluic acid under O2 (1 atm) in the presence of THICA (5 mol %) and Co(OAc)2 (0.5 mol %) at 100 °C were smoothly oxidized to the corresponding benzoic acids in almost quantitative yields. The aerobic oxidation of toluene by THICA was compared with that by N-hydroxyphthalimide. p-Xylene was efficiently oxidized by THICA to telephthalic acid in high yield (over 95%) under mild conditions.