957070-16-5

Basic information

• Product Name: tert-butyl 4-(2-methoxy-1-{[methyl(phenyl)amino]sulfonyl}-2-oxoethyl)benzoate
• Synonyms: tert-butyl 4-(2-methoxy-1-{[methyl(phenyl)amino]sulfonyl}-2-oxoethyl)benzoate
• CAS NO: 957070-16-5
• Molecular Weight: 419.499
• Mol File: 957070-16-5.mol

Chemical Properties

• CAS DataBase Reference: tert-butyl 4-(2-methoxy-1-{[methyl(phenyl)amino]sulfonyl}-2-oxoethyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 4-(2-methoxy-1-{[methyl(phenyl)amino]sulfonyl}-2-oxoethyl)benzoate(957070-16-5)
• EPA Substance Registry System: tert-butyl 4-(2-methoxy-1-{[methyl(phenyl)amino]sulfonyl}-2-oxoethyl)benzoate(957070-16-5)

Safety Data

• Hazardous Substances Data: 957070-16-5(Hazardous Substances Data)

Upstream product

• 59247-47-1 tert-butyl-4-bromobenzoate 
• 117765-67-0 methyl {[methyl(phenyl)amino]sulfonyl}acetate 

Relevant articles and documents

A new strategy for the synthesis of benzylic sulfonamides: Palladium-catalyzed arylation and sulfonamide metathesis

(Chemical Equation Presented) An efficient two-step strategy has been developed to access diversely functionalized benzylic sulfonamides. Execution of this strategy required the development of two reaction methods: the palladium-catalyzed cross-coupling of aryl halides with CH-acidic methanesulfonamides and a metathesis reaction between the resulting α-arylated sulfonamides and diverse amines. The broad scope of the cross-coupling process combined with a versatile sulfonamide metathesis constitutes an efficient strategy for the synthesis of various benzylic sulfonamides.