95872-23-4Relevant academic research and scientific papers
Formation of Quinol Ethers using (Diacetoxyiodo)benzene
Lewis, Norman,Wallbank, Philip
, p. 1103 - 1106 (2007/10/02)
The use of (diacetoxyiodo)benzene for the oxidative coupling of a hindered phenol with aliphatic alcohols or other phenols has been investigated.
Some Rearrangements of 2,4,6-Tri-t-butyl-4-nitrocyclohexa-2,5-dienone
Hartshorn, Michael P.,Kennedy, James A.,Simpson, Richard W.,Vaughan, John,Wright, Graeme J.
, p. 735 - 743 (2007/10/02)
Rearrangement of 2,4,6-tri-t-butyl-4-nitrocyclohexa-2,5-dienone (20) in benzene gives the 4-hydroxy dienone (21) and the mono-de-t-butylated 1,2-benzoquinone (22).The rearrangement is not affected by the addition of mesitylene, but the phenol-coupling product (26) is formed in the presence of p-cresol, and the nitromethyl phenol (31) is formed when the nitro dienone (20) rearranges in the presence of 2,4,6-trimethylphenol (29).The rearrangements of the nitro dienone (20) in methanol are described.
