96009-79-9

Basic information

• Product Name: cyclohexyl-5 pentanolide-4
• Synonyms: cyclohexyl-5 pentanolide-4
• CAS NO: 96009-79-9
• Molecular Weight: 182.263
• Mol File: 96009-79-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: cyclohexyl-5 pentanolide-4(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl-5 pentanolide-4(96009-79-9)
• EPA Substance Registry System: cyclohexyl-5 pentanolide-4(96009-79-9)

Safety Data

• Hazardous Substances Data: 96009-79-9(Hazardous Substances Data)

Upstream product

• 4904-55-6 cyclohexanecarbonyl peroxide 
• 84210-61-7 perpentene-4 oate de tertiobutyle 
• 39716-58-0 pent-4-enoyl chloride 
• 2049-80-1 (2-propenyl)propanedioic acid diethyl ester 
• 591-80-0 pent-4-enoic acid 
• 117508-82-4 peroxyde de cyclohexanecarbonyle et de pentene-4 oyle 
• 110-82-7 cyclohexane 

Relevant articles and documents

DEPLACEMENTS HOMOLYTIQUES INTRAMOLECULAIRES-16-DECOMPOSITION DES PEROXYDES ET PERESTERS INSATURES PAR LES RADICAUX CYCLOHEXYLE ISSUS DE DERIVES PEROXIDIQUES DE L'ACIDE CYCLOHEXANECARBOXYLIQUE

Thermolyses of dicyclohexyl carbonyl peroxide have been performed in organic solutions of t-butyl pent-4-enyl peroxide or t-butyl perpent-4-enoate in order to study the induced decomposition by cyclohexyl radicals of these peroxides.Induced decomposition of cyclohexylcarbonyl pent-4-enoyl peroxide and pent-4-enyl cyclohexylpercarboxylate has also been studied.In the decomposition of these compounds, SHi reaction of an acyloxy radical is involved which is, to our knowledge, the first example of such reaction with a perester.

INTRAMOLECULAR HOMOLYTIC DISPLACEMENTS 7 - FREE RADICAL ADDITIONS TO UNSATURATED PEROXY COMPOUNDS : SYNTHESIS OF OXYGENATED HETEROCYCLES

Free radical additions of hydrogen donor solvents to tert-butyl perpent-4-enoate have given 4-substituted γ-butyrolactones, with yields of 50 percent or greater.Such reactions applied to allyl-tert-butyl peroxide have produced 2,3-epoxypropanation of these solvents.Similar addition-elimination processes occurred with tert-butyl 4-methyl-perpent-4-enoate, tert-butyl 2,2-dimethyl-perpent-4-enoate and tert-butyl-methallyl peroxide, but they failed with tert-butyl 5-methyl-perhex-4-enoate and tert-butyl-3-methyl-but-2-enyl peroxide.