Cas 96190-99-7,(C2H4)2(H2O)Ir(PC18H13)2(1+)*BF4(1-)=(C2H4)2(H2O)Ir(PC18H13)2BF4

96190-99-7

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Product Name: (C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2⁽¹⁺⁾*BF₄^(1-)=(C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2BF₄
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CAS NO:96190-99-7
Molecular Formula:
Molecular Weight: 873.697
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CAS DataBase Reference: (C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2⁽¹⁺⁾*BF₄^(1-)=(C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2BF₄(CAS DataBase Reference)
NIST Chemistry Reference: (C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2⁽¹⁺⁾*BF₄^(1-)=(C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2BF₄(96190-99-7)
EPA Substance Registry System: (C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2⁽¹⁺⁾*BF₄^(1-)=(C₂H₄)2(H₂O)Ir(PC₁₈H₁₃)2BF₄(96190-99-7)

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Hazardous Substances Data: 96190-99-7(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 96190-99-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,6,1,9 and 0 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 96190-99:
(7*9)+(6*6)+(5*1)+(4*9)+(3*0)+(2*9)+(1*9)=167
167 % 10 = 7
So 96190-99-7 is a valid CAS Registry Number.

96190-99-7Upstream product

96190-99-7Downstream Products

96190-99-7Relevant academic research and scientific papers

OBSERVATIONS ON OLEFIN OXIDATION BY NEUTRAL AND CATIONIC PHOSPHINEIRIDIUM COMPLEXES

Brown, John M.,John, Robert A.,Lucy, Andrew R.

, p. 245 - 258 (2007/10/02)

The ethyleneiridium oxygen complex ClIr(PPh3)2(O2)(C2H4) previously prepared by Van der Ent, decomposes in solution forming some Ph3PO and CH3CHO, in the absence of excess ethylene.It promotes the oxidation of 1-octene and styrene by O2 and factors affecting the rate and efficiency of oxidation have been examined.Tetrastyrene di-μ-chlorodiiridium is only oxidised effectively by O2 in the presence of PPh3.The 1-octene complex ClIr(PPh3)2(C8H16) reacts very rapidly with oxygen at low temperatures but 2-octanone is not found in the decomposition products.The cationic complex (C2H4)Ir+(PPh3)2 promotes the oxidation of 1-octene and styrene but low yields of products are formed, including phenyloxirane and benzaldehyde.Complexes of 5-phenyldibenzophosphole were examined.They are not effective in promoting oxidation and display a strong tendency to form stable five-coordinate complexes and a greater propensity for cis-biphosphine coordination.

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