96249-84-2

Basic information

• Product Name: 2-Propyn-1-one, 1-(6-hydroxy-1,3-benzodioxol-5-yl)-3-phenyl-
• CAS NO: 96249-84-2
• Molecular Formula: C16H10O4
• Molecular Weight: 266.253
• Mol File: 96249-84-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propyn-1-one, 1-(6-hydroxy-1,3-benzodioxol-5-yl)-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propyn-1-one, 1-(6-hydroxy-1,3-benzodioxol-5-yl)-3-phenyl-(96249-84-2)
• EPA Substance Registry System: 2-Propyn-1-one, 1-(6-hydroxy-1,3-benzodioxol-5-yl)-3-phenyl-(96249-84-2)

Safety Data

• Hazardous Substances Data: 96249-84-2(Hazardous Substances Data)

Upstream product

• 7299-58-3 phenylpropiolyl chloride 
• 533-31-3 Sesamol 
• 75-44-5 phosgene 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Metal Template ortho-Acylation of Phenols. Direct Synthesis of Salicylic Acid Chlorides and Derivatives

A direct synthesis of salicylic acid chlorides is achieved via "metal-driven" intracomplex acylation of bromomagnesium and aluminum phenoxides with phosgene.Salicylic acids 5 and some derivatives 6, 7 can be obtained by quenching the reaction mixture with convenient reagents.Moreover the reaction of lithium phenylacetylide with 3 provides a new convenient approach to ortho-hydroxyaryl alkynyl ketones like 8.The oriented complex 2, involving the metal phenoxide and phosgene is proposed to account for the ortho-regioselective control of the reaction.