96256-40-5Relevant academic research and scientific papers
Studies on Organic Fluorine Compounds. XLI. The Friedel-Crafts Reaction of Trifluoropropene
Kobayashi, Yoshiro,Nagai, Takabumi,Kumadaki, Itsumaro,Takahashi, Masaaki,Yamauchi, Takashi
, p. 4382 - 4387 (2007/10/02)
The Friedel-Crafts reaction of 1,1,1-trifluoropropene with benzene and its derivatives was accomplished in the presence of fluorine-containing acid catalysts.The reaction proceeded at the terminal carbon atom of the olefin to give 3,3,3-trifluoropropylated aromatic compounds.The scope and limitations of this reaction were examined.This substituent was found to be ortho- and para-directing.Keywords - Friedel-Crafts reaction; trifluoropropene; trifluoropropyl; Nafion-H; hydrogen fluoride; boron trifluoride; tetrafluoroboric acid; benzene; trifluoropropylation
