96540-34-0

Basic information

• Product Name: 3-Furancarboxylic acid, tetrahydro-4-(iodophenylmethyl)-2-oxo-, ethyl ester
• CAS NO: 96540-34-0
• Molecular Formula: C14H15IO4
• Molecular Weight: 374.175
• Mol File: 96540-34-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Furancarboxylic acid, tetrahydro-4-(iodophenylmethyl)-2-oxo-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Furancarboxylic acid, tetrahydro-4-(iodophenylmethyl)-2-oxo-, ethyl ester(96540-34-0)
• EPA Substance Registry System: 3-Furancarboxylic acid, tetrahydro-4-(iodophenylmethyl)-2-oxo-, ethyl ester(96540-34-0)

Safety Data

• Hazardous Substances Data: 96540-34-0(Hazardous Substances Data)

Upstream product

• 96540-32-8 1-ethoxycarbonyl-3-oxa-2-oxo-6-phenylbicyclo<3.1.0>hexane 
• 146743-99-9 cinnamyl ethyl α-diazomalonate 
• 96540-63-5 cinnamyl ethyl malonate 

Downstream Products

• 22530-98-9 4-benzyl-dihydro-furan-2-one 
• 16720-76-6 4-(phenylmethyl)-2(5H)-furanone 
• 96540-42-0 3-carbonyl-4-benzyl-4,5-dihydrofuran-2(3H)-one 
• 96540-46-4 4-benzyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one 
• 96540-49-7 4-benzyl-3-phenylsulfinyl-4,5-dihydrofuran-2(3H)-one 
• 96540-38-4 3-ethoxycarbonyl-4-benzyl-4,5-dihydrofuran-2(3H)-one 

Relevant articles and documents

Synthesis of 4-Alkyl-2(5H)-furanones

An alternative method for the synthesis of 4-alkyl-2(5H)-furanones is described.Intramolecular carbene addition reaction of α-diazo compounds (4) in the presence of rhodium acetate or copper acetylacetonate furnished the bicyclic compounds (5), which were subjected to cyclopropane ring-opening reaction to give the 4-alkyl-4,5-dihydrofuran-2(3H)-ones (6) regioselectively.These compounds (6) were further converted into 4-alkyl-2(5H)-furanones (14) in several steps.Keywords - carbene; intramolecular addition; butenolide; cyclopropanation; ring-opening reaction